I fortunately had friends to explain and show me the basics, and considering i play it almost exclusively with them - yes, it will be actually palatable with friends.
The learning curve would be the hardest part, but if you have general MOBA knowledge it shouldn't be too hard.
On the other hand the main theme of Arcane was don't download league of legends
I mean, give it a go if it's (still?) for you? Matches can be quick, they're doing a new map for the next season soon and bad actors can be muted.
I think it's a decent game just with horrid monetisation currently
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But also try the card game you meaningfully interact with the game's universe so much more than you do in league
On the other hand the main theme of Arcane was don't download league of legends
I think it's a decent game just with horrid monetisation currently