ARAR and MNHR can stay a very long time in the mines without losing stability. The ARAR is an efficient blacksmith and can retrieve voxels from splitting just like with clay, if you mess something up. MNHR gets more out of ore and has a short-range ore scanner, she also spawns with heavy armor.
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LSTR is a good scout and can reveal the location of an underground ruin during expeditions, she can also craft survey charges (recipe TBD.)
Those are my ideas so far.