Old rockets, like the space shuttle main engine, used to burn hydrogen and oxygen, producing water. Instead, SpaceX rockets burn methane. Each of these Starship rockets produces over 3000 tons of carbon dioxide, assuming it doesn't just explode and release the methane instead.
People asking about starship's carbon footprint, I don't do space but here's reporting from folks who do: "Starship, because it's the biggest rocket ever built, is also one of the dirtiest."

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