I can see how Sigil would be useful to tinker under the hood, if one were so inclined, but it looks like it'd be awful to actually create the ebook in the first place. I've reverted to Scrivener, whose foibles are irritating but at least vaguely familiar.
Comments
The key thing with Scrivener is working out the proper settings for compilation, and then it's largely fine (though I've never looked under the hood to see just _how_ fine its output is).