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The Organic Chemistry Portal - For daily updates please visit https://www.organic-chemistry.org/abstracts/ and check out https://www.organic-chemistry.org/info/linking/
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www.organic-chemistry.org/abstracts/li... A visible-light-induced aerobic oxidative hydroxylation of arylboronic acids/pinacol esters

www.organic-chemistry.org/abstracts/li... A Cu-catalyzed degree-controlled deacylative deuteration of diverse alkyl groups

www.organic-chemistry.org/abstracts/li... A Co(III)-catalyzed redox-neutral annulation of benzamides and acrylamides with vinylene carbonate

www.organic-chemistry.org/abstracts/li... An operationally simple direct δ-amination reaction of sp3 C-H bonds, employing molecular iodine (I2) as the sole oxidant

www.organic-chemistry.org/abstracts/li... A mild, rapid, straightforward visible-light-mediated sulfonamide ethylation of easily available redox active esters

www.organic-chemistry.org/abstracts/li... A mild, rapid, and selective copper-catalyzed Csp-S cross-coupling of thiols and bromoalkynes

www.organic-chemistry.org/Highlights/2... Douglass features The Magauer Synthesis of Waixenicin A

www.organic-chemistry.org/abstracts/li... An asymmetric construction of challenging acyclic α,α-disubstituted α-chlorinated ketimines

www.organic-chemistry.org/abstracts/li... An efficient iridium-catalyzed acceptorless dehydrogenative coupling (ADC) reaction of 2-aminoarylmethanols and amides

www.organic-chemistry.org/abstracts/li... Potassium 1,1,3,3-tetranitropropane-1,3-diide reacts readily with various (hetero)aryl amines

www.organic-chemistry.org/abstracts/li... A modular and transition-metal-free, aryne-induced three-component coupling protocol allows the facile synthesis of structurally diverse N-aryl (iso)quinolones

www.organic-chemistry.org/abstracts/li... Sodium benzene sulfinate catalyzed a visible-light-driven aerobic oxidative cleavage of olefins

www.organic-chemistry.org/abstracts/li... An efficient copper-mediated cleavage of isoxazoles enables the synthesis of nicotinate derivatives

www.organic-chemistry.org/abstracts/li... A practical and efficient copper-catalyzed carbocyclization of 2-functionalized anilines with ethyl bromodifluoroacetate

www.organic-chemistry.org/abstracts/li... A Simmon-Smith reaction of alkenyl 1,2-bis(boronates) for the stereodefined synthesis of cyclopropyl-1,2-bis(boronates)

www.organic-chemistry.org/abstracts/li... C(sp3)-H dehydrogenative cross-couplings of ethers, tetrahydrothiophenes, and pyrrolidines with alcohols

www.organic-chemistry.org/abstracts/li... A 1,4-alkylcyanation of enynes with cyclic alcohol derivatives in the presence of trimethylsilyl cyanide (TMSCN)

www.organic-chemistry.org/abstracts/li... The combination of Fe3+/H2O2 mediates a regioselective alkylation or arylation of alkenes with sulfoxides

www.organic-chemistry.org/abstracts/li... XtalFluor-E promotes a deoxofluorination reaction of carboxylic acids

www.organic-chemistry.org/abstracts/li... An improved one-pot, two-step reaction of trimethylsulfoxonium iodide and reactive carboxylic acid derivatives

www.organic-chemistry.org/abstracts/li... A facile hydrosilylation-deoxygenation of ketones, aldehydes, acetals, alcohols, ethers, and silyl ethers

www.organic-chemistry.org/abstracts/li... Pyridinium 1,4-zwitterionic thiolates with sulfenes generated in situ provide either 3H-1,2-dithiole 2,2-dioxides or...

www.organic-chemistry.org/abstracts/li... Gold/chiral amine relay catalysis enables a mild and effective asymmetric synthesis of C2-quaternary indolin-3-ones

www.organic-chemistry.org/abstracts/li... A general palladium-catalyzed carbonylative synthesis of acyl fluorides

www.organic-chemistry.org/abstracts/li... Potassium carbonate promotes a convenient hydrophosphonylation of alkenes with phosphites in good yields.

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www.organic-chemistry.org/abstracts/li... Acetophenone promotes a highly selective, efficient, and simple direct transamidation of thioamides with amines

www.organic-chemistry.org/abstracts/li... Acceptorless dehydrogenative coupling reactions of 1,3-diols with arylhydrazines to provide pyrazoles and 2-pyrazolines in good yields

www.organic-chemistry.org/abstracts/li... A diaryldiselenide catalyzes a cross-dehydrogenative nucleophilic functionalization of hydrophosphoryl compounds.

www.organic-chemistry.org/abstracts/li... Mild reaction conditions for efficient and highly regio- and enantioselective hydroboration of α-alkyl- and α-aryl- acrylates

www.organic-chemistry.org/abstracts/li... Electrocatalytic three-component acylcyanations and aminocyanations of a broad range of simple alkenes

www.organic-chemistry.org/abstracts/li... A Cu-catalyzed hydroalumination of readily accessible allenes with diisobutylaluminum hydride followed by tandem nucleophilic addition to aldehydes/Oppenauer oxidation

www.organic-chemistry.org/abstracts/li... The use of an oxazaborolidinium ion catalyst for a highly stereoselective synthesis of (Z)-silyl enol ethers

www.organic-chemistry.org/abstracts/li... An alkoxide base promotes a deborylative phosphination of benzylic organoboronates and geminal bis(boronates)

www.organic-chemistry.org/abstracts/li... Cbz, Alloc, and methyl carbamate protected amines can be readily deprotected by treatment with 2-mercaptoethanol

www.organic-chemistry.org/abstracts/li... A metal-free electrochemical intramolecular C(sp2)-H amination using iodine as a mediator

www.organic-chemistry.org/abstracts/li... An enantioselective difunctionalization of activated alkynes using chiral sulfinamide reagents

www.organic-chemistry.org/abstracts/li... An electroreductive protocol for the radical fluorosulfonylation of vinyl triflates with FSO2Cl as the fluorosulfonyl radical source

www.organic-chemistry.org/abstracts/li... A highly efficient asymmetric intermolecular Ni-catalyzed reductive dicarbofunctionalization of vinyl amides, vinyl boranes, or vinyl phosphonates

www.organic-chemistry.org/Highlights/2... Douglass features Arrays of Stereogenic Centers: The Tong Synthesis of Spirohexenolide B

www.organic-chemistry.org/abstracts/li... A practical base-promoted tandem condensation N-alkylation reaction of aldehydes and hydrazines with alkyl halides

www.organic-chemistry.org/abstracts/li... An enantioselective iridium-catalyzed allylic alkylation of malonates with trisubstituted allylic electrophiles

www.organic-chemistry.org/abstracts/li... A Cu-catalyzed C-H fluorination with N-fluorobenzenesulfonimide (NFSI)

www.organic-chemistry.org/abstracts/li... Photoactivation of an electron donor-acceptor (EDA) complex for a radical hydro-fluorosulfonylation of propargyl alcohols

www.organic-chemistry.org/abstracts/li... A perfluorophenyl substituted 1,1′-bi-2-naphthol (BINOL) is an effective photoacid catalyst for promoting the acetalization of enol ethers

www.organic-chemistry.org/abstracts/li... Various sulfone tetrazoles were activated via iridium photoredox catalysis in the presence of DMAP to give dialkyl sulfones.

www.organic-chemistry.org/abstracts/li... Two structurally related 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands enable the regiodivergent arylation of styrenes.

www.organic-chemistry.org/abstracts/li... The use of Oxone/aluminum trichloride mixture enables an α,α-dichlorination of β-keto esters and 1,3-diketones in aqueous medium.

www.organic-chemistry.org/abstracts/li... The L-proline-based amphiphile PS-750-M enables extremely fast amide couplings in water